The round of 64 line up has been released with NesTea kicking it off on the first play day, and the Emperor finalizing the round of 64 on the final play day of the round on November the 25th.

GSL Season 3 - Round of 64
November 22nd, 11:00 CET
Player 1Bo3Player 2GosuBet
 IMNesTeaVs. Jys- GosuBet
Maps: 1. Shakuras Plateau 2. Delta Quadrant 3. Xel'Naga Caverns
oGsVinesVs. SEn- GosuBet
Maps: 1. Steppes of War 2. Delta Quadrant 3. Blistering Sands
LittleBoyVs. JookToJung- GosuBet
Maps: 1. Shakuras Plateau 2. Blistering Sands 3. Xel'Naga Caverns
MakaPrimeVs. Sleep- GosuBet
Maps: 1. Xel'Naga Caverns 2. Steppes of War 3. Jungle Basin
oGsTheWindVs. GoldenfOu- GosuBet
Maps: 1. Xel'Naga Caverns 2. Shakuras Plateau 3. Scrap Station
November 23rd, 05:00 CET
Player 1Bo3Player 2GosuBet
 RacheVs. ST_BoggieBoy- GosuBet
Maps: 1. Steppes of War 2. Xel'Naga Caverns 3. Jungle Basin
DreamizErZenithVs. TSL_Rain- GosuBet
Maps: 1. Shakuras Plateau 2. Jungle Basin 3. Xel'Naga Caverns
LiberoPrimeVs. NsP_Genius- GosuBet
Maps: 1. Metalopolis 2. Xel'Naga Caverns 3. Shakuras Plateau
TSL_RainbOwVs. NewDawn- GosuBet
Maps: 1. Metalopolis 2. Shakuras Plateau 3. Xel'Naga Caverns
BitByBitPrimeVs. LiquidHayprO- GosuBet
Maps: 1. Blistering Sands 2. Scrap Station 3. Xel'Naga Caverns
November 23rd, 11:00 CET
Player 1Bo3Player 2GosuBet
 TosyadVs. FruitDealer- GosuBet
Maps: 1. Scrap Station 2. Jungle Basin 3. Metalopolis
ScfOuVs. Bless- GosuBet
Maps: 1. Metalopolis 2. Lost Temple 3. Scrap Station
anyproPrimeVs. TheBestfOu- GosuBet
Maps: 1. Lost Temple 2. Steppes of War 3. Metalopolis
NEXNayaVs. HounUnPrime- GosuBet
Maps: 1. Delta Quadrant 2. Metalopolis 3. Jungle Basin
November 24th, 05:00 CET
Player 1Bo3Player 2GosuBet
 LiquidRetVs. Cyrano- GosuBet
Maps: 1. Lost Temple 2. Jungle Basin 3. Metalopolis
JSLZenithVs. KyrixZenith- GosuBet
Maps: 1. Delta Quadrant 2. Scrap Station 3. Xel'Naga Caverns
BoxeRVs. NEXLine- GosuBet
Maps: 1. Delta Quadrant 2. Metalopolis 3. Jungle Basin
gumihoVs. ST_Monster- GosuBet
Maps: 1. Shakuras Plateau 2. Xel'Naga Caverns 3. Delta Quadrant
TSL_GuineaPigVs. IMJunwi- GosuBet
Maps: 1. Shakuras Plateau 2. Steppes of War 3. Jungle Basin
November 24th, 11:00 CET
Player 1Bo3Player 2GosuBet
 TSL_ClideVs. LeenockfOu- GosuBet
Maps: 1. Jungle Basin 2. Lost Temple 3. Shakuras Plateau
ST_MaxVs. oGsHyperdub- GosuBet
Maps: 1. Blistering Sands 2. Scrap Station 3. Delta Quadrant
oGsMCVs. OdinMvP- GosuBet
Maps: 1. Jungle Basin 2. Shakuras Plateau 3. Xel'Naga Caverns
ST_JulyVs. cOreZenith- GosuBet
Maps: 1. Shakuras Plateau 2. Delta Quadrant 3. Steppes of War
November 25th, 05:00 CET
Player 1Bo3Player 2GosuBet
 aLivefOuVs. oGsZenio- GosuBet
Maps: 1. Lost Temple 2. Jungle Basin 3. Metalopoli
PoltPrimeVs. NsP_Joon- GosuBet
Maps: 1. Delta Quadrant 2. Scrap Station 3. Xel'Naga Caverns
LiquidJinroVs. NEXDrug- GosuBet
Maps: 1. Delta Quadrant 2. Metalopolis 3. Jungle Basin
LibertyVs. ButterflyEffect- GosuBet
Maps: 1. Shakuras Plateau 2. Xel'Naga Caverns 3. Delta Quadrant
EGIdrAVs. NEXChoa- GosuBet
Maps: 1. Shakuras Plateau 2. Steppes of War 3. Jungle Basin
November 25th, 11:00 CET
Player 1Bo3Player 2GosuBet
 IMMVPVs. BanbanssuZenith- GosuBet
Maps: 1. Scrap Station 2. Metalopolis 3. Scrap Station (?)
AnnyungPrimeVs. ChoyafOu- GosuBet
Maps: 1. Jungle Basin 2. Metalopolis 3. Shakuras Plateau
DestinationVs. CheckPrime- GosuBet
Maps: 1. Scrap Station 2. Steppes of War 3. Lost Temple
SlayerS_BoxeRVs. NEXOn- GosuBet
Maps: 1. Steppes of War 2. Shakuras Plateau 3. Delta Quadrant
Note: Some of the races may be wrong, and the map pool might change.

Links
GOMTV.net - Source (English)
PlayXP.com - Source (Korean)